Atletico Madrid were held to a 1-1 draw at home by Valencia and missed the chance to return to second in La Liga.
Substitute Iker Muniain secured all three points for Athletic Bilbao as they shocked Valencia 1-0 in La Liga at the San Mames.
Ricardo Costa nodded the winner in stoppage time as Valencia came from behind to complete a 3-2 win over nine-man Deportivo.
Real Madrid destroyed a hapless Valencia side courtesy of a five-star first half performance in a 5-0 romp at the Mestalla.
Valencia earned a nervy win over Granada CF as Pablo Piatti provided a late strike at Estadio Los Cármenes to secure a 2-1 victory.
Ernesto Valverde’s reign as Valencia manager began with a 1-0 win at Osasuna thanks to Roberto Soldado's second-half strike.
Valencia's attacking midfielder Pablo Piatti will be out of action for eight to 10 weeks after breaking his right arm in training.
Valencia demolished Real Betis 4-0 in La Liga to warm up for Thursday's task of overturning a 4-2 Europa League semi-final deficit.
Getafe put a spanner in Valencia's Champions League ambitions with a 3-1 Liga victory at the Coliseum Alfonso Perez.
Valencia conceded two late goals in a 4-2 Europa League last-16 first leg victory over PSV Eindhoven at the Mestalla.
Lionel Messi helped himself to four goals as Barcelona came from behind to defeat Valencia 5-1 and solidify second place in La Liga.
Mehmet Topal's spectacular long-range strike gave Valencia a 1-0 victory over Stoke in the first leg of their last-32 Europa League tie.
Valencia dropped more points in La Liga as they were held to a goalless draw by Atletico Madrid at the Estadio Vicente Calderon.
Pablo Piatti led Valencia to a 3-0 win at local rivals Levante in the second leg of their Copa del Rey quarter-final, a 7-1 aggregate win.
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